Sulfur isotope fractionation during growth of sulfate-reducing bacteria on various carbon sources   总被引：1，自引：0，他引：1  

Jutta Kleikemper  Martin H. Schroth  Benjamin Brunner 《Geochimica et cosmochimica acta》2004,68(23):4891-4904

Stable sulfur isotope fractionation during microbial sulfate reduction is a potential tool to estimate sulfate reduction rates at field sites. However, little is known about the influence of the utilized carbon source on the magnitude of sulfur isotope fractionation. To investigate this effect, both a pure culture (strain PRTOL1) and enrichment cultures from a petroleum hydrocarbon (PHC)-contaminated aquifer were used and grown in batch cultures on various carbon sources with an initial sulfate concentration of 1 mmol/L. As sole carbon sources the PHC components naphthalene, 1,3,5-trimethylbenzene, and heating oil (enrichment culture) and the organic acids acetate, pyruvate, benzoate, and 3-phenylpropionate (enrichment culture and PRTOL1) were used. Sulfate reduction rates of all cultures ranged from 6 ± 1 nmol cm⁻³ d⁻¹ (enrichment culture grown on 1,3,5-trimethylbenzene) to 280 ± 6 nmol cm⁻³ d⁻¹ (enrichment culture grown on pyruvate). Cell-specific sulfate reduction rates ranged from 1.1 × 10⁻¹⁴ mol cell⁻¹ d⁻¹ (PRTOL1 grown on pyruvate) to 1.5 × 10⁻¹³ mol cell⁻¹ d⁻¹ (PRTOL1 grown on acetate). Sulfur isotope enrichment factors (ε) for the enrichment culture ranged from 16.1‰ (3-phenylpropionate) to 34.5‰ (1,3,5-trimethylbenzene) and for PRTOL1 from 30.0‰ (benzoate) to 36.0‰ (pyruvate). Cultures of PRTOL1 always showed higher ε values than the enrichment culture when grown on the same carbon source due to culture-specific properties. Higher ε values were obtained when the enrichment culture was grown on PHC components than on organic acids. No relationship between ε values and cell-specific sulfate reduction rate existed when all data were combined. When comparing the magnitude of ε values determined in this laboratory study with ε values measured at contaminated and uncontaminated field sites, it becomes evident that a multitude of factors influences ε values at field sites and complicates their interpretation. The results of this study help us assess some of the general parameters that govern the magnitude of ε in sulfate-reducing environments.  相似文献   

Nation states, ideological power and globalisation: can geographers catch the boat?     

Martin Jones  Rhys Jones 《Geoforum》2004,35(4):409-424

After a period of considerable and sustained hegemony, many commentators have argued that contemporary processes of globalisation are acting as a challenge to nation state sovereignty. The paper argues that geographers need to focus on the ways in which the nation state continues to act, albeit in a modified manner, within the era of globalisation. This might help to position geography within globalisation debates, which--according to Dicken [Geographers and `globalization': (yet) another missed boat? forthcoming, Transactions of the Institute of British Geographers, 2004]--we have not been centrally involved in. Drawing on the work of Michael Mann, we focus on a neglected dimension of state power--namely, its ideological form--as a means of exploring how the nation state is being differentially re-engineered under globalisation. Using Mann's classification of forms of ideological organisation, we deploy three vignettes in order to demonstrate the evolving nature of ideological power within the contemporary UK State.  相似文献   

A pulsed extension model for the Neogene–Recent E–W-trending Alaşehir Graben and the NE–SW-trending Selendi and Gördes Basins, western Turkey     

Martin Purvis  Alastair Robertson   《Tectonophysics》2004,391(1-4):171

We have developed a significant body of new field-based evidence relating to the history of crustal extension in western Turkey. We establish that two of the NE–SW-trending basins in this region, the Gördes and Selendi Basins, whose sedimentary successions begin in the early Miocene, are unlikely to relate to late-stage Alpine compressional orogeny or to E–W extension of Tibetan-type grabens as previously suggested. We argue instead that these basins are the result of earlier (?) late Oligocene, low-angle normal faulting that created approximately N–S “scoop-shaped” depressions in which clastic to lacustine and later tuffaceous sediments accumulated during early–mid-Miocene time, separated by elongate structural highs. These basins were later cut by E–W-trending (?) Plio–Quaternary normal faults that post-date accumulation of the Neogene deposits. In addition, we interpret the Alaşehir (Gediz) Graben in terms of two phases of extension, an early phase lasting from the early Miocene to the (?) late Miocene and a young Plio–Quaternary phase that is still active. Taking into account our inferred earlier phase of regional extension, we thus propose a new three-phase “pulsed extension” model for western Turkey. We relate the first two phases to “roll-back” of the south Aegean subduction zone and the third phase to the westward “tectonic escape” of Anatolia.  相似文献   

Intraplate seismicity in SE Brazil: stress concentration in lithospheric thin spots   总被引：1，自引：0，他引：1  

Marcelo Assumpção  Martin Schimmel  Christian Escalante  José Roberto Barbosa  Marcelo Rocha  Lucas V. Barros 《Geophysical Journal International》2004,159(1):390-399

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Volcanic resurfacing and the early terrestrial crust: Zircon U-Pb and REE constraints from the Isua Greenstone Belt, southern West Greenland     

Balz Samuel Kamber  Martin J. Whitehouse  Stephen Moorbath 《Earth and Planetary Science Letters》2005,240(2):276-290

The oldest known bona fide succession of clastic metasediments occurs in the Isua Greenstone Belt, SW Greenland and consists of a variety of mica schists and rare metaconglomerates. The metasediments are in direct contact with a felsic metavolcanic lithology that has previously been dated to 3.71 Ga. Based on trace element geochemical data for > 30 metasediments, we selected the six samples with highest Zr concentrations for zircon extraction. These samples all yielded very few or no zircon. Those extracted from mica schists yielded ion probe U/Pb ages between 3.70 and 3.71 Ga. One metaconglomerate sample yielded just a single zircon of 3.74 Ga age.The mica schist hosted zircons have U/Pb ages, Th / U ratios, REE patterns and Eu anomalies indistinguishable from zircon in the adjacent 3.71 Ga felsic metavolcanic unit. Trace element modelling requires the bulk of material in the metasediments to be derived from variably weathered mafic lithologies but some metasediments contain substantial contribution from more evolved source lithologies. The paucity of zircon in the mica schists is thus explained by incorporation of material from largely zircon-free volcanic lithologies. The absence of older zircon in the mica schists and the preponderance of mafic source material imply intense, mainly basaltic resurfacing of the early Earth. The implications of this process are discussed.Thermal considerations suggest that horizontal growth of Hadean crust by addition of mafic-ultramafic lavas must have triggered self-reorganisation of the protocrust by remelting. Reworking of Hadean crust may have been aided by burial of hydrated (weathered) metabasalt due to semi-continuous addition of new voluminous basalt outpourings. This process causes a bias towards eruption of Zr-saturated partial melts at the surface with O-isotope compositions potentially different from the mantle. The oldest zircons hosted in sediments would have been buried to substantial depth or formed in plutons that crystallised at some depth, from which it took hundreds of millions of years for them to be exhumed and incorporated into much younger sediments.  相似文献   

Temporal and spatial cyclicity of accretion at slow-spreading ridges—evidence from the Reykjanes Ridge     

Christine Peirce  Alex Gardiner  Martin Sinha 《Geophysical Journal International》2005,163(1):56-78

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Compositional variations (major and trace elements) of clinopyroxene and Ti-andradite from pyroxenite, ijolite and nepheline syenite, Alnö Island, Sweden     

Jaana Hode Vuorinen  Ulf H  lenius  Martin J. Whitehouse  Joakim Mansfeld  Alasdair D.L. Skelton 《Lithos》2005,81(1-4):55-77

Clinopyroxenes from pyroxenite, ijolite and nepheline syenite from the main intrusion of the Alnö complex define two sub-parallel compositional trends with respect to Na, Ca and Fe_TOT plotted against alkali-pyroxene fractionation index (Na–Mg). Both trends define a smooth fractionation of increasing Na and Fe_TOT and decreasing Ca with increasing Na–Mg, but one set of samples contain clinopyroxenes that constantly plot at higher Na and lower Fe_TOT and Ca (at similar Na–Mg) than the rest of the samples. Clinopyroxenes with higher Ca and Fe_TOT and lower Na (trend 1) co-exist with substantial amounts of Ti-andradite (up to 70 vol.%), while the sample set defining the more Na-rich trend (trend 2) lack co-existing Ti-andradite. Clinopyroxenes from both trends show fractionated REE patterns with a distinct difference in HREE content, reflecting the content of co-existing Ti-andradite. The rocks of the first Ti-andradite-bearing trend crystallized slightly prior to the rocks of the second trend, probably from a primitive, Ca- and Ti-rich nephelinitic magma. Crystallisation of pyroxenite and melteigite occurred under low aSiO₂ and high aCaO and aTiO₂ as evidenced by the presence of perovskite and sometimes substantial amounts of magnetite. Subsequent increase in aSiO₂ is evidenced in the overgrowth of perovskite by titanite, which in turn is overgrown by Ti-andradite. Nepheline syenitic residuals crystallized under higher aSiO₂ and aNa₂O and lower aCaO and aTiO₂, which reduced Ti-andradite into an accessory phase and produced more Si- and Na-rich clinopyroxenes. Some of these residuals probably also mixed with new primitive magma producing a hybrid magma that crystallised the more Na-rich and Ca- and Fe_TOT-poor clinopyroxenes of trend 2. The complete lack of Ti-andradite in these rocks indicates different crystallisation conditions and also a different magma composition.  相似文献   

Dynamic characteristics analysis of shallow landslides in response to rainfall event using GIS     

H. X. Lan  C. F. Lee  C. H. Zhou  C. D. Martin 《Environmental Geology》2005,47(2):254-267

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A high-resolution TEM-AEM, pH titration, and modeling study of Zn coprecipitation with ferrihydrite     

Stacin Martin  Chen Zhu  Joseph Rule  Robert Ford  Yee Soong 《Geochimica et cosmochimica acta》2005,69(6):1543-1553

Experiments of Zn²⁺ and Fe³⁺ coprecipitation as a function of pH were conducted in the laboratory at ambient temperature and pressure. X-ray diffraction patterns of the coprecipitates show two broad peaks at 0.149 and 0.258 nm, which is consistent with published patterns for pure 2-line ferrihydrite. Zn²⁺ uptake occurred at pH ≥5 while Fe³⁺ precipitation occurred between pH 3 and 4, although both Zn²⁺ and Fe³⁺ were present in the same solution during the entire range of pH titration. High-resolution transmission electron microscopy shows that the coprecipitates are 2 to 6 nm sized single crystalline particles but aggregated to 50 to 400 nm sized clusters. Analytical electron microscopy indicated that the 5% atomic Zn with respect to Fe was homogeneously distributed. No segregated phases were found in the clusters or at single crystal edges, which is consistent with published extended X-ray absorption fine structure (EXAFS) results at similar Zn/(Zn + Fe) ratios. Hence, occlusion and surface precipitation may be excluded as possible coprecipitation mechanisms. The bulk solution Zn²⁺ sorption edge was fitted to both solid solution and generalized diffuse layer surface complexation models. However, a solid solution model is inconsistent with published EXAFS results that show tetrahedral polydentate Zn²⁺ complexes sharing apices with Fe³⁺octahedra.  相似文献   

Modeling the impact of microbial activity on redox dynamics in porous media     

Martin Thullner  Philippe Van Cappellen  Pierre Regnier 《Geochimica et cosmochimica acta》2005,69(21):5005-5019

The present study investigates the interaction between microbial growth and activity and the redox dynamics in natural porous media. The impact the transport regime has on this interaction is also addressed. Expressions for microbial growth are incorporated into a geochemical reaction network linking redox reaction rates to the activity of the microorganisms. A flexible simulation environment, the Biogeochemical Reaction Network Simulator (BRNS) is used for this purpose. Two reactive transport applications relevant to fields of contaminant hydrology and early diagenesis are simulated with the BRNS. Model results are evaluated based on a comparison with comprehensive datasets on the biodegradation of lactate in a sand column experiment and on the distribution of redox-sensitive chemical species in marine sediments of the Skagerrak, Denmark. It is shown that, despite quite different transport regimes, the geomicrobiological model performs equally well in the reproduction of measured chemical species distribution for both applications. This result emphasizes the broad applicability of the proposed approach. Our simulations support that the competitive behavior between various microbial groups is a process controlling the development of redox stratified environments. Furthermore, it is also shown that the transport regime is a key controlling factor for the degree of spatial correlation between microbial biomass distributions and redox reaction rates. Although all our simulations yield a pronounced stratification of the redox processes in the system, the biomass distribution is related to the associated reaction rates only in case of the advection controlled column experiment. In the early diagenetic application, mixing due to bioturbation is the dominant transport process for particulate matter, hence leading to fairly homogeneous distribution of bacterial biomasses which are unrelated to the spatial distribution of redox reaction rates. This homogeneous biomass distribution combined with the 1G carbon degradation model approach might explain why the steady state concentration profiles in such systems can be reproduced by diagenetic models without explicit representation of microbial growth.  相似文献